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Preparative-scale regio- and stereospecific oxidoreduction of cholic acid and dehydrocholic acid catalyzed by hydroxysteroid dehydrogenases

โœ Scribed by Riva, Sergio; Bovara, Roberto; Pasta, Piero; Carrea, Giacomo

Book ID
126837233
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
650 KB
Volume
51
Category
Article
ISSN
0022-3263

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โœ Ruth Naigre; Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 434 KB

Palladium acetate immobilized on montmorillonite is an effective catalyst for the carbonylation of secondary allylic alcohols with carbon monoxide, in the presence of triphenylphosphine and an acid promoter, affording P,y-unsaturated acids in 39-56% isolated yields. The reaction is regio-and stereos