Preparations and properties of thermosensitive terpolymers of N-isopropylacrylamide, sodium 2-acrylamido-2-methyl-propanesuphonate, and N-tert-butylacrylamide

✍ Scribed by Dan Shao; Caihua Ni

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 406 KB
• Volume: 105
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.26275

✦ Synopsis

Abstract

Terpolymers based on N‐isopropylacrylamide, sodium 2‐acrylamido‐2‐methyl‐propanesulfonate, and N‐tert‐butylacrylamide were synthesized by free‐radical copolymerization with 2,2′‐azobisisobutyronitrile as an initiator. The lower critical solution temperatures (LCSTs) of the linear polymer aqueous solutions were determined by the measurement of the transmittance on UV at different temperatures. The influence of the polymer concentration, polymer composition, and ionic strength on the LCSTs of the linear polymers was investigated. The LCST decreased with increases in the hydrophobic monomer N‐tert‐butylacrylamide, polymer concentration, and ionic strength. The phase transition became sharp when the polymer concentration and ionic strength increased. Meanwhile, the crosslinked hydrogels were prepared with the same recipe used for the linear terpolymers, but a crosslinker was added to the reaction system. The swelling ratios of the hydrogels at various temperatures and salt solutions were determined. The hydrogels possessed both high swelling ratios and thermosensitivity. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007