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Preparation, Structures, and Some Reactivities of Five-Coordinate Alkyne Complexes of Mo with Tetraphosphine or Diphosphine Coligand [Mo(RCCR′){ meso - o -C 6 H 4 (PPhCH 2 CH 2 PPh 2 ) 2 }] and [Mo(RCCR′)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ]

✍ Scribed by Niikura, Fumiya; Seino, Hidetake; Mizobe, Yasushi


Book ID
125975774
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
261 KB
Volume
28
Category
Article
ISSN
0276-7333

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Metallacrown ethers with trans-tetracarb
✍ Christina H Duffey; Charles H Lake; Gary M Gray 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 263 KB

Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac