The Reaction of Polyhalides with Allylsilanes Catalyzed by Copper(I) Chloride. -Allyltrimethylsilane (I) reacts with polyhalogen compounds (II) in the presence of copper species affording polyhalo compounds containing an allyl group. Other allylsilanes, e.g. (IV), (VI), and (IX), give various produ
✦ LIBER ✦
Preparation of Vinylsilanes Through the Reaction of Polyhalides with α-Halogen Substituted Allylsilanes Catalyzed by Copper(I) Chloride.
✍ Scribed by Michiharu Mitani; Masayuki Masuda; Akihiko Inoue
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 33 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Tertiary amines with three different substituents, in one of which a vinylsilane functionality was included, were straightforwardly formed by the copper(I) chloride‐catalyzed tandem reaction of primary amines, α‐halogen‐substituted allylsilanes, and electrophiles such as electron‐defici
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