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Preparation of Vinylsilanes Through the Reaction of Polyhalides with α-Halogen Substituted Allylsilanes Catalyzed by Copper(I) Chloride.

✍ Scribed by Michiharu Mitani; Masayuki Masuda; Akihiko Inoue


Publisher
John Wiley and Sons
Year
2004
Weight
33 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ M. MITANI; S. HUJITA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

The Reaction of Polyhalides with Allylsilanes Catalyzed by Copper(I) Chloride. -Allyltrimethylsilane (I) reacts with polyhalogen compounds (II) in the presence of copper species affording polyhalo compounds containing an allyl group. Other allylsilanes, e.g. (IV), (VI), and (IX), give various produ

Copper(I) Chloride-Catalyzed Three-Compo
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## Abstract Tertiary amines with three different substituents, in one of which a vinylsilane functionality was included, were straightforwardly formed by the copper(I) chloride‐catalyzed tandem reaction of primary amines, α‐halogen‐substituted allylsilanes, and electrophiles such as electron‐defici