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Preparation of ultrafine RuO2IrO2TiO2 oxide particles by a sol—gel process

✍ Scribed by Yoshio Takasu; Satoshi Onoue; Kohichi Kameyama; Yasushi Murakami; Kiyochika Yahikozawa


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
799 KB
Volume
39
Category
Article
ISSN
0013-4686

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✦ Synopsis


Six specimens of ultrafine RuO2-IrO2-TiO 2 ternary oxide particles with different content ratios have been prepared by a sol-gel method using metal alkoxides. Only a RuO2-rich specimen was composed of a mixture of futile-type oxide phase and a metallic phase, while the other specimens were composed of only rutile-type oxide phase after calcination of them in air at 450°C for 3 h. The comparison of the XRD spectra of these ternary oxide particles with those of ternary oxide films prepared by a conventional dip-coating method on titanium plate substrates suggested that the oxide particles tended to attain more stable state than the oxide films.


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