Menthol templated vinyl-functionalized organosilica materials were prepared by acid catalyzed hydrolytic sol-gel reactions of tetraethyl orthosilicate and vinyltriethoxysilane. The menthol template was removed by sublimation under vacuum, leading to the formation of a mesoporous organosilica materia
Preparation of TiO2 microcoils from carbon microcoil templates using a sol–gel process
✍ Scribed by S. Motojima; T. Suzuki; Y. Noda; A. Hiraga; H. Iwanaga; T. Hashishin; Y. Hishikawa; S. Yang; X. Chen
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 449 KB
- Volume
- 378
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Novel TiO 2 microcoils were obtained by coating TiO 2 layers on the carbon microcoil templates by using a sol-gel process. The preparation conditions, morphologies, microstructure, and some properties were examined. It was found that helical TiO 2 fibers, including TiO 2 microcoils (TMCs) or TiO 2 microtubes with negative coiling patterns on the surface (TMCNCs) were obtained, depending on the coating conditions. TMCNCs were formed when used low concentrations of titanium tetra-isopropoxide in ethanol, while TMCs were formed when used high concentrations.
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Six specimens of ultrafine RuO2-IrO2-TiO 2 ternary oxide particles with different content ratios have been prepared by a sol-gel method using metal alkoxides. Only a RuO2-rich specimen was composed of a mixture of futile-type oxide phase and a metallic phase, while the other specimens were composed