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Preparation of the laevorotatory trans-(4S,6S)-4,6-dimethyl-1,3-dithiane and trans-(4S,6S)-4,6-dimethyl-1,3-oxathiane. An internal displacement of a secondary sulphonate leading to a cyclic thioacetal

✍ Scribed by D. Danneels; M. Anteunis; L. van Acker; D. Tavernier


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
479 KB
Volume
31
Category
Article
ISSN
0040-4020

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✍ Annaβ€…M. PiΔ…tek; Agnieszka Chojnacka; Christian Chapuis; Janusz Jurczak πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 167 KB

## Abstract The now corrected X‐ray structure of (2__R__)‐bornane‐10,2‐sultam ((βˆ’)‐**1a**), as well as that of its already published __N__‐crotonoyl derivative (βˆ’)‐**1d**, were compared with those of the newly synthesized (2__R__)‐fenchane‐8,2‐sultam ((+)‐**5a**), as well as its __N__‐crotonoyl der