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Preparation of the 4-ethylamino sugar of calicheamicin: Assignment of absolute configuration.

โœ Scribed by Daniel Kahne; Dan Yang; May D Lee

Book ID
104226444
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
148 KB
Volume
31
Category
Article
ISSN
0040-4039

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Stereoselective synthesis of amphiasteri
Stereoselective synthesis of amphiasterin B4: assignment of absolute configuration
โœ Masaki Takahashi; Takamasa Suzuki; Jolanta Wierzejska; Tetsuya Sengoku; Hidemi Y ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 314 KB

The first asymmetric synthesis of (+)-amphiasterin B4 was completed from a known (S)-b-benzyloxy-clactone. Comparison with the spectroscopic properties reported for authentic material has given a clear indication as to the absolute stereochemistry of the natural amphiasterin B4.