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Preparation of soluble N and o-alkylated polyanilines using a chemical biphasic process

✍ Scribed by A. Falcou; A. Longeau; D. Marsacq; P. Hourquebie; A. Duchêne

Book ID
117542922
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
222 KB
Volume
101
Category
Article
ISSN
0379-6779

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✍ Martin J.P. Harger; P.Andrew Shimmin 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 847 KB

Abstruct : Treatment of &,P(O)Cl with MesSiNI-IOSiM~ gives Pr$P(0)NHOSiMes. which is desilylated by methanol giving P&P(O)NHOH. The 0-p-nitrobenz.enesulphonyI derivative of this rearranges with KOBu' in BuYIH, an isopropyl group migrating from P to N and the phosphonamidate R'P(O)(OBu?NIIpi being fo