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Preparation of Ru(CO)(diene)2 Complexes by Electron-Beam Evaporation of Ruthenium. Preliminary Communication

✍ Scribed by David N. Cox; Raymond Roulet

Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
162 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis

Ru-atoms (0.5-1.5 g) have been generated by electron bombardment and, in separate experiments, were co-condensed at 77 K with excess of 2,3-dimethylbutadiene or 1,3-or 1,4-~yclohexadiene. The complexes Ru(CO)(q 4-C,H,,), (1) and Ru(CO)(r;14-C,H,), (2), respectively, have been isolated in 25-30% yields on warming the condensate under CO.

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