To ileitl cffcctivcly wit!t cvcit the gctteriil iispccts of hoth phiit i i n t l niiiniiil I)ioclic~nistry witltiit tlic spricc of less t l i i i n 500 pages is iit itself no ltleiili tiisk. IVIien this sonicwhiit c1:ist.i~ titlc is iillo~vod to iiicliitlc ii consitlcriilde study of the p r c iiritl
Preparation of pure inorganic substances. By E. H. Archibald. Pp. x + 383. New York: J. Wiley & Sons; London: Chapman and Hall, Ltd., 1932. 23s
โ Scribed by Robinson, P. L.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1932
- Weight
- 144 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0368-4075
No coin nor oath required. For personal study only.
โฆ Synopsis
with statcnicnt and nutliority in tlic trniIitionn1 style.
Erirlicr pnrts alrciitly publishcd hnrc ilcnlt with the nictnl itself iind niucli of its chcniistry, so tlint licrc \YO find the cynnidcs, tlic compounds with n fcw, nininly Pourtli nntl Fifth Group, clcnicnts, nntl tlic nnnlyticnl clienlistry of iron only consitlcrcd. Tlic first nncl last of thcsc topics occupy tlic grciitcr part of tlic tcst. Fcrroiintl fcrri-cyrinitlcs of tlinnd tri-vnlcnt iron nnd of ninny otlier clcincnts and rndicnls nrc dcscribctl in great dctnil 110th ns to preparation and properties. Espccinl sections nrc dcvotctl to sricli of tlicsc compounds :is find IISC ns pipnicnts : tlicir colour, constitution, nnd colloidal propertics rccciw a trent incnt befitting their intliistrinl importance. A nnmbcr of coinplcs cynnidcs of organic radicals iirc tlcscril~ctl. Tliio-nntl nitrosocyanitlcs nrc nilequiitcly dcnlt with on siinilnr lincs although natiirnlly nt not so grciit n length ns the sfmigltl coniplcs cynnirlcs.
Sections follow dcvotetl to tlic conipouiids of iron contnining silicon, pliosplioriis, nrsciiic, niit iiiioiiy, and lismutli ; siicli as, for csaniplc, silicntes, donblc linlidcs ant1 the likc, but not tlic two-clcnicnt systcnis wliich wcrc dcscribcd in parts of tlic volume nlrcndy publishcd.
The concluding portion is n lcngtliy rind presuinn1)ly complctc account of those reactions of iron of cspccinl interest in its dctcction ant1 cstimntion. In addition to n fnithful rccoiinting of tlicsc renctions, tlic conditions gorcrning oxidntion and rcductioii arc cnrcfully considered and osidntioii potent ids, soliil~ilitics, :ind otlicr pli.sico-cliciiiicnl data of nnnlyticiil utility given in the fullest possible ninniicr.
Workers using this book will iiot occrisionnlly hnvc the satisfnction of finding what is usually rcfcrrctl to rather loosely ns ~y u l i c e evidctice r~liich may siirc t lien1 n great dcnl of trouble.
1'. L. l<ourssos PHEPARATIOS OF PIJRP: ISORoASIC SUUSTASCES.
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sioiis," iiiicl thc niitlior of tlic ~o r k iiiitlcr review, ii pupil of I\'o. Ostwiild, obscrrcs tlint iiow t,liosc cliiiiciisioiis cnii 110 loiigcr bc iicglcctcd. The title " Kolloidik," u. wortl siiggcstctl by K. Spiro, is iiitciided to cover tlic physics niitl cliciiiistry of colloids, iiiitl tl
for work a t tlic Rotlinnistcd 1Sspcriiiicntnl Station, Ha rpciiden. 'I'hc Trllstccs l ~n v c rcneivcd tltc following Fcllowsliips for tlic session 1929-30 :-Dr. H. Uienfsit (Nctherlnntl Fcl~owship), for work n t tlic Iinperinl Collcgc of Scicncc and 'I cchnolopy, Lontlon. Ilr. l'ctcr Naitlnntl (Gln