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Preparation of primary alcohols from organolithium compounds and paraformaldehyde

✍ Scribed by A. Schaap; L. Brandsma; J. F. Arens

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
113 KB
Volume
84
Category
Article
ISSN
0165-0513

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Preparation of alcohols from sulfones an
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✍ CΓ©lia Billaud; Jean-Philippe Goddard; Thierry Le Gall; Charles Mioskowski πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 129 KB

The reaction of sulfone anions with trialkylboranes followed by thermal isomerization of the obtained boron compounds in the presence of excess borane-methyl sulfide complex and by alkaline hydroperoxide oxidation yields primary alcohols.