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Preparation of Alcohols from Sulfones and Trialkylboranes.

✍ Scribed by Celia Billaud; Jean-Philippe Goddard; Thierry Le Gall; Charles Mioskowski

Publisher
John Wiley and Sons
Year
2003
Weight
104 KB
Volume
34
Category
Article
ISSN
0931-7597

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Preparation of alcohols from sulfones an
Preparation of alcohols from sulfones and trialkylboranes
✍ CΓ©lia Billaud; Jean-Philippe Goddard; Thierry Le Gall; Charles Mioskowski πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 129 KB

The reaction of sulfone anions with trialkylboranes followed by thermal isomerization of the obtained boron compounds in the presence of excess borane-methyl sulfide complex and by alkaline hydroperoxide oxidation yields primary alcohols.