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Preparation of phosphorous acid from phosphorus
- Publisher
- Elsevier Science
- Year
- 2002
- Weight
- 31 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1351-4180
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β¦ Synopsis
Process could reduce costs for terephthalic acid
Lurgi, Eastman, and SK have developed a process for making terephthalic acid (PTA) which might achieve savings of $50/tonne. The mild oxidation leads to less byproducts. Other advantages include use of the heat of reaction, simple recovery of catalyst, and recycling of solvent. The process gives extremely low concentrations of p-toluic acid. A 500,000 tonne/y plant would cost $226 M rather than $280 M using traditional technology.
π SIMILAR VOLUMES
Amidoalkylation of phospbarous acid by the reaction of mixture of phosphorous acid and amide with carbonyl compounds in acetic anbdri. de, followed by hydrolysis to give l-aminoalkanephosphonic acids, is described.
Activated carbons were prepared from rice hull by one-step phosphoric acid activation in this work. The evolution of pore structure and surface chemistry in the activation temperature range of 170-450 Β°C was investigated through various characterization techniques. The results showed that the develo