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Preparation of Pd(PPh2H)2(PPh3)2and its Role as a Precursor of a Dinuclear Complex with Bridging Phosphide Ligands

✍ Scribed by Masumi Itazaki; Yasushi Nishihara; Kohtaro Osakada


Book ID
106547053
Publisher
Springer
Year
2005
Tongue
English
Weight
157 KB
Volume
30
Category
Article
ISSN
0340-4285

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The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho