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Preparation of Optically Active Polyhedral Borane Derivatives

✍ Scribed by Hertler, W. R.


Book ID
127241942
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
268 KB
Volume
86
Category
Article
ISSN
0002-7863

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The preparation of optically active 3-fl
✍ J.T. Welch; R. Kawecki; J.A. Wichtowski; K. Araki πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 33 KB

Optically active 3-fluoro+lactam (1) was stereoselectively synthesized by the ketene-imine condensation method. Use of (1) in alkylation and aldol reactions resulted in the stereoselective formation of ( 2) and ( 3) respectively, but the control of the hydroxylated stereocenter was not possible in