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Chemoenzymatic preparation of optically active anthracene derivatives

✍ Scribed by F. Javier Quijada; Javier González-Sabín; Francisca Rebolledo; Vicente Gotor

Book ID
108284400
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
201 KB
Volume
19
Category
Article
ISSN
0957-4166

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A series of (R)-and (S)-l-alkyn-3-ols, chiral building units for the synthesis of leukotrienes and pheromones, were prepared via enantioselective hydrolysis of their racemic esters. While the majority of biocatalysts employed (lipases, fermenting or freezedried microorganisms) failed in discriminati