✦ LIBER ✦

Preparation of optically active allylsilanes by catalytic asymmetric hydrosilylation of 1-arylbutadienes1

✍ Scribed by Tamio Hayashi; Keiji Kabeta

Book ID: 104228759
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 228 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98608-8

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✦ Synopsis

Asymmetric hydrosilylation of l-arylbutadienes with trichlorosilane in the presence of a chiral ferrocenylphosphine-palladium catalyst gave optically active allylsilanes, (z)-laryl-1-silyl-Z-butenes and their regioisomers.

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