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Preparation of novel multifunctional amino alcohols from nitroparaffins and α,β-unsaturated aldehydes

✍ Scribed by Asghar A. Peera; Ian A. Tomlinson

Book ID
113930812
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
473 KB
Volume
53
Category
Article
ISSN
0040-4039

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Preparation of chiral propargylic alcoho
Preparation of chiral propargylic alcohols from α,β-unsaturated esters
✍ Jiong Chun; Hoe-Sup Byun; Robert Bittman 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 143 KB

A series of chiral propargylic alcohols with high enantiomeric excess was prepared by asymmetric dihydroxylation of a,b-unsaturated esters, conversion of the diols to 4-(chloromethyl)-1,3-dioxolane intermediates, and base-induced elimination.