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Preparation of nitramine-nitrates by ring-opening nitration of azetidines by dinitrogen pentoxide (N2O5)

โœ Scribed by Peter Golding; Ross W. Millar; Norman C. Paul; David H. Richards


Book ID
107857773
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
598 KB
Volume
51
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Nitration by Oxides
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Nitration by Oxides of Nitrogen. Part 10. Clean Nitrations: Novel Syntheses of Nitramines and Nitrate Esters by Nitrodesilylation Reactions Using Dinitrogen Pentoxide (N2O5). -29 Examples are given for the novel nitration where N2O5 in an inert solvent is used to cleave heteroatom-silicon bonds to

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## Reaction of medium ring cyclic ethers with N205 in halogenated solvents gave only low yields of the corresponding dinitrates. On the other hand, cyclic formals (1,3dioxolane and its homologues) gave moderate yields of unstable ring-opened products (hemiformal nitrates), together with variable a