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Preparation of indan-1-one and 1-methyl-4,5-benzindan-3-one

✍ Scribed by Aziz-Ur Rahman; Alicia E. Gastaminza

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
248 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The methods of preparation of indan‐1‐one and 1‐methyl‐4,5‐benzindan‐3‐one have been reviewed; the former has been prepared by Friedel‐Craft's condensation of β‐chloropropionyl chloride and benzene via β‐chloropropiophenone, while the latter was obtained by the cyclisation of β‐2‐naphthylbutyric acid, prepared either, by malonic ester synthesis on α‐chloro‐α‐(2‐naphthyl)ethane or by a Reformatsky reaction on 2‐acetylnaphthalene.

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