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Preparation of Heterobimetallic Complexes with a Bridging Dinitrogen Ligand, [WX(PMe2Ph)4(.mu.-N2)MCp2Cl] (M = Ti, X = Cl; M = Zr, and Hf, X = I), and X-ray Structure of [WI(PMe2Ph)3(py)(.mu.-N2)ZrCp2Cl] (py = pyridine)

✍ Scribed by Mizobe, Yasushi; Yokobayashi, Youhei; Oshita, Hiroyuki; Takahashi, Tamotsu; Hidai, Masanobu


Book ID
126141113
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
293 KB
Volume
13
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES


Copper(I) complexes with a dibasic nitro
✍ Anne-Marie Larsonneur; Reine Turpin; Pierre FertΓ©; Paule Castan; Gerald Bernardi πŸ“‚ Article πŸ“… 1994 πŸ› Springer 🌐 English βš– 498 KB

The reaction of CuC1 or CuX 2 (X = C1 or NO3) with NPm (diphenylphosphinodiphenylaminomethane) yields molecular P-bonded copper(I) complexes of general formula CuL2X. These complexes are isostructural. For both complexes the coordination geometry around the copper atom is almost trigonal planar and