Preparation of gelatin–N-vinylpyrrolidone graft copolymer

✍ Scribed by Jianping Gao; Zhichong Li; Wei Wang; Mingzhi Huang

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 188 KB
• Volume: 68
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19980531)68:9<1485::aid-app11>3.0.co;2-z

✦ Synopsis

The graft copolymerization of N-vinylpyrrolidone (VP) onto gelatin was carried out by the following four different initiator systems: AIBN, K 2 S 2 O 8 , H 2 O 2 {Fe 2/ , and Ce 4/ {HNO 3 . The last one caused the monomer to lose the doublebond and polymerization ability due to the hydrolysis of the monomer. Using a,aazobisisobutyronitrile as an initiator, the graft copolymerization of gelatin and N-vinylpyrrolidone in aqueous medium was studied systematically. The relationships between the rate of grafting and the concentration of initiator, monomer, and gelatin were established experimentally. Meanwhile, the rate equation was also derived from the proposed reaction mechanism, and it was similar to the equation previously obtained experimentally. The apparent activation energies for homopolymerization ( E h ), graft copolymerization ( E g ), and over all polymerization (E p ) were calculated. The graft efficiency and molecular weight of the grafted PVP were measured by hydrolyzing the backbone with hydrochloric acid. The graft copolymers Gel-g-PVP were added into the coating films, and the physical properties of the films, such as hardening ability, dimensional stability, and wetting property were investigated.