The graft copolymerization of N-vinylpyrrolidone (VP) onto gelatin was carried out by the following four different initiator systems: AIBN, K 2 S 2 O 8 , H 2 O 2 {Fe 2/ , and Ce 4/ {HNO 3 . The last one caused the monomer to lose the doublebond and polymerization ability due to the hydrolysis of the
Graft copolymerization of N-vinylpyrrolidone onto gelatin
β Scribed by Jian-Ping Gao; Zhi-Chong Li; Ming-Zhi Huang
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 387 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The graft copolymerization of N-vinylpyrrolidone (VP) onto gelatin in aqueous medium, with a,d-azobisisobutylonitrile as initiator, has been studied. The effects of various reaction parameters such as temperature, reaction time, as well as the concentrations of initiator, monomer, and gelatin on the percentage of grafting and grafting efficiency were also studied. The chain-transfer constant of isopropanol in this system was calculated. Finally, the grafted samples were analyzed with IR, DSC, TEM, and SEM measurements.
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Crosslinked poly(N-vinylpyrrolidone) (PVPy) beads were irradiated with β₯-rays in air from a 60 Co source. Preirradiated beads were grafted with polyacrylamide by refluxing with acrylamide in water or dioxane. Conditions for optimum grafting were determined under a variety of reaction parameters, suc
In order to improve upon certain properties of gelatin graft copolymerization of acrylonitrile ( A N ) and methacrylonitrile (MAN) onto gelatin has been studied in aqueous medium using y rays as a source of initiation. Optimum conditions for affording maximum percentage of grafting have been evaluat