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Preparation of fluoroacrylate nanocopolymer by miniemulsion polymerization used in textile finishing

✍ Scribed by Pei-Yuan Huang; Yu-Chou Chao; Yih-Tyan Liao


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
72 KB
Volume
94
Category
Article
ISSN
0021-8995

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Bulk polymerization of styrene with oligododecandioyl peroxide (ODDP) was studied and the overall rate constant, k, was found as 8.4. lo-' at 60Β°C and 5.1 I 10e4 (l/mol)'~\*sec-' at 80Β°C. Active polystyrene containing peroxy groups (0.93 wt%) was obtained by the polymerization of styrene with ODDP a