✦ LIBER ✦

Preparation of electrically conducting polypyrrole in oil/water microemulsion

✍ Scribed by Feng Yan; Gi Xue; Mingshi Zhou

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 163 KB
Volume: 77
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(20000705)77:1<135::aid-app18>3.0.co;2-b

No coin nor oath required. For personal study only.

✦ Synopsis

Nanoscopic conducting polypyrrole powder was prepared in an oil/water microemulsion with FeCl 3 as a dopant. Compared with solution and conventional emulsion polymerizations, a microemulsion polymerization system increases the yield of the resultant polypyrrole. The results of FTIR spectra and thermal analysis studies indicate that the microemulsion polymerization system increased the extent of the -conjugation length along the polymer backbone and ordered the arrangement of the macromolecule chains. These two effects bring about enhanced conductivity as well as higher thermal stability of polypyrrole.

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