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Photoinitiated copolymerization of acrylamide and styrene in oil-in-water microemulsion

✍ Scribed by Liping Zhang; Zhaohua Zeng; Yonglie Chen; Chi Wu; Jun Gao


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
165 KB
Volume
66
Category
Article
ISSN
0021-8995

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✦ Synopsis


This article describes the copolymerization of acrylamide with styrene in oil-in-water microemulsion, using dodecyl betaine as emulsifier and a-hydroxy-a,adimethyl acetophenone or a,a-dimethoxy-phenyl acetophenone as photoinitiator. Results indicated that the photoinitiation of polymerization occurs at the interface between the oil phase and the water phase and that the polymerization occurs in the microemulsion droplet. Particle size increased with increasing polymerization time. The copolymer chain consisted of isolated acrylamide units randomly distributed among styrene groups.


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