𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Preparation of deuteriated benzylamines and phenethylamine with raney alloys in an alkaline deuterium oxide solution

✍ Scribed by Takehito Tsukinoki; Hirohisa Tsuzuki; Keiko Ishimoto; Kouji Nakayama; Takaaki Kakinami; Shuntaro Mataka; Masashi Tashiro

Publisher
John Wiley and Sons
Year
1994
Tongue
French
Weight
259 KB
Volume
34
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Benzyl‐α,α‐^2^H~2~‐amine, 2‐^2^H~1~‐Benzyl‐α,α‐^2^H~2~‐amine, 3‐^2^H~1~‐Benzyl‐α,α‐^2^H~2~‐amine, 4‐^2^H~1~‐Benzyl‐α,α‐^2^H~2~‐amine, 2, 5‐^2^H~2~‐Benzyl‐α,α‐^2^H~2~‐amine, and phenethyl‐α,α,β,β‐^2^H~4~‐amine were prepared in high isotopic purities from the corresponding benzonitrile, bromobenzonitriles, and phenylacetonitrile by reduction with Raney Cu‐Al alloy in an alkaline deuterium oxide solution.

📜 SIMILAR VOLUMES

Preparation of benzyl-α-D1-alcohol by th
Preparation of benzyl-α-D1-alcohol by the reduction of benzaldehyde with raney alloys in an alkaline deuterium oxide solution
✍ Takehito Tsukinoki; Keiko Ishimoto; Hirohisa Tsuzuki; Shuntaro Mataka; Masashi T 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 French ⚖ 186 KB

## Abstract Benzyl‐α‐d~1~‐alcohol was prepared in high isotopic purity by the reduction of benzaldehyde with Raney Cu‐Al alloy in 10% Na~2~CO~3~‐D~2~O solution using ultrasonic irradiation.

Preparation of deuterated naphthalenes,
Preparation of deuterated naphthalenes, anilines, m-toluidines, and anisoles by reductive dehalogenation of the corresponding halogenated derivatives with raney Cu-Al alloy in an alkaline deuterium oxide solution
✍ Masashi Tashiro; Hirohisa Tsuzuki; Takehito Tsukinoki; Shuntaro Mataka; Kouji Na 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 French ⚖ 336 KB

## Abstract Four deuterated naphthalenes, ten deuterated anilines, three deuterated m‐toluidines, and five deuterated anisoles were prepared in high isotopic purities from the corresponding halo‐substituted derivatives by the reductive dehalogenation with Raney Cu‐Al alloy in an alkaline deuterium