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Preparation of deuteriated adipic [2H2]-, [2H4]-, [2H6]-, and [2H8]-acids by use of kolbe electrolysis as a key reaction

✍ Scribed by Masashi Tashiro; Hirohisa Tsuzuki; Hideyuki Goto; Shoji Ogasahara; Shuntaro Mataka

Publisher
John Wiley and Sons
Year
1990
Tongue
French
Weight
385 KB
Volume
28
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Using Kolbe electrolysis of methyl hydrogen [^2^H~0~]‐, [^2^H~2~]‐, and [^2^H~4~]‐succinates as a key reaction, adipic [2,2‐^2^H~2~]‐, [2,3‐^2^H~2~]‐, [2,2,3,3‐^2^H~4~]‐, [2,3,4,5‐^2^H~4~]‐, [2,3,5,5‐^2^H~4~]‐, [2,2,3,3,5,5‐^2^H~6~]‐, and [2,2,3,3,4,4,5,5‐^2^H~8~]‐acids were prepared in high deuterium contents.

πŸ“œ SIMILAR VOLUMES

Preparation of 4-phenylbutyric [2,3-2H2]
Preparation of 4-phenylbutyric [2,3-2H2]-, [4,4-2H2]-, [2,3,4,4-2H4]-, and [2,2,3,3,4,4-2H6]-acids by use of crossed kolbe electrolysis as a key reaction
✍ Masashi Tashiro; Hirohisa Tsuzuki; Hideyuki Goto; Shoji Ogasahara; Shuntaro Mata πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 French βš– 301 KB

## Abstract The four deuteriated 4‐phenylbutyric [2,3‐^2^H~2~]‐, [4,4‐^2^H~2~]‐, [2,3,4,4‐^2^H~4~]‐, and [2,2,3,3,4,4‐^2^H~6~]‐acids have been synthesized in high isotopic purity by utilizing crossed Kolbe electrolysis of methyl hydrogen [^2^H~0~]‐, [2,3‐^2^H~2~], and [2,3,3,3‐^2^H~4~]‐succinates a