𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Preparation of chiral stationary phases based on anionically polymerised (4S,5S)-4-methyl-5-phenyl-2-(4-vinylphenyl)-2-oxazoline

✍ Scribed by Gerald Terfloth; Gottfried Blaschke

Book ID
102483544
Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
316 KB
Volume
195
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

(4__S__,5__S__)‐4‐methyl‐5‐phenyl‐2‐(4‐vinylphenyl)‐2‐oxazoline(1) was prepared. The anionic polymerisation of 1 was initiated in toluene with butyllithium (BuLi) at −78°C to afford poly(1) of narrow molecular weight distribution. The resulting poly(1) was immobilised on modified silica gel to give chiral stationary phases for the separation of racemic compounds.

📜 SIMILAR VOLUMES

Preparation and evaluation of chiral sta
Preparation and evaluation of chiral stationary phases based on N,N-2,4-(or 4,6)-disubstituted 4,5-(or 2,5)-dichloro-1,3-dicyanobenzene
✍ Darko Kontrec; Vladimir Vinković; Vitomir Šunjić 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB 👁 1 views

Regioselective functionalization of 2,4,5,6-tetrachloro-1, 3-dicyanobenzene (TCDCB) by nucleophilic substitution of the chlorine at C(4) with L-Ala, L-Phe or L-Pro, followed by amide-bond formation to lipophilic amines containing strong pi-donor group, and by final introduction of the spacer 3-amino

ChemInform Abstract: Self-Addition Produ
ChemInform Abstract: Self-Addition Products from the Alkylation of Amino Acid-Derived Oxazolidinones: X-Ray Molecular Structures of (2R,4S,1′S)-3-Benzoyl-4-( benzoylamino(phenyl)methyl)-4-benzyl-2-phenyl-1,3-oxazolidin-5-one (IV) , (2R,4S,1′S)- (VI), and (2R,4S,1′R)-3-Benzoyl-4-(benzoylamino(phenyl) methyl)-4-isopropyl-2-phenyl-1,3-oxazolidin-5-one (VII).
✍ A. D. ABELL; J. M. TAYLOR; M. D. OLDHAM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB