Preparation of chiral diimino- and diaminodiphosphine ligands and their CuI and AgI complexes. X-ray crystal structures of [Cu(1S,2S-cyclohexyl-P2N2)][PF6] and [Ag(1R,2R-cyclohexyl-P2N2H4)][BF4]
✍ Scribed by Wai-Kwok Wong; Tat-Wai Chik; Kin-Ning Hui; Ian Williams; Xue Feng; Thomas C.W. Mak; Chi-Ming Che
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 1001 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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📜 SIMILAR VOLUMES
Synthesis and crystal structure of 1,6-Bis-(N,Ndiethylaminothiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexane are reported as well as those of its dimeric Ag I complex (as monotoluene adduct of the diperchlorate) and its tetrameric l-tetrabromo Ag I complex.
## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_