## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
✦ LIBER ✦
Preparation of Bicyclic 1,2,4-Trioxanes from γ,δ-Unsaturated Ketones
✍ Scribed by Ramirez, Armando P.; Thomas, Andrew M.; Woerpel, K. A.
- Book ID
- 120343636
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 124 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1523-7060
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## Abstract With __t__‐BuO^−^/__t__‐BuOH at 185°C bicyclo‐[2.2.2] and ‐[3.2.1]octanones are interconvertible. In saturated systems equilibrium is attained very slowly, but in unsaturated cases an equilibrium mixture heavily favoring the [3.2.1] skeleton is obtained relatively rapidly, thereby provi