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Preparation of Arylmercapturic Acids by S-Arylation of N,N′-Diacetylcystine

✍ Scribed by Jan Krouželka; Igor Linhart

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 269 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200900982

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✦ Synopsis

A simple convenient method has been developed for the preparation of N-acetyl-S-arylcysteines based on the Chan-Lam-Evans arylation of N,NЈ-diacetylcystine dimethyl ester with arylboronic acids and used to synthesize a series of arylmercapturic acids. Unlike copper-mediated N-arylation, the

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