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Preparation of and Fluoroalkylation with (Chlorodifluoromethyl)trimethylsilane, Difluorobis(trimethylsilyl)methane, and 1,1,2,2-Tetrafluoro-1,2-bis(trimethylsilyl)ethane

✍ Scribed by Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.


Book ID
120036425
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
363 KB
Volume
119
Category
Article
ISSN
0002-7863

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0.75 g, 15 mmol) and chlorotrimethylsilane (3.15 mL, 25 mmol) in dry acetonitrile (25 mL). The progress of the reactions was monitored by IR, and they were complete in 6-8 h. Pure silyl nitronates were obtained after workup and characterized by their NMR and IR spectra. Silyl nitronate of 6a: 1.0 g