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Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

โœ Scribed by Jesse R. McAtee; Sara E. S. Martin; Derek T. Ahneman; Keywan A. Johnson; Prof. Donald A. Watson

Book ID
112000800
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
415 KB
Volume
51
Category
Article
ISSN
0044-8249

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Palladium-catalyzed reaction of u-substituted Y-trimethylsilylated allylic carbonates with carbonucleophiles took place regioselectively at the a-carbon. Reaction of formic acid took place at Y-carbon to afford allylic