Palladium-catalyzed regioselective reactions of silyl-substituted allylic carbonates and vinyl epoxide

✍ Scribed by Jiro Tsuji; Masami Yuhara; Makoto Minato; Hisao Yamada; Fumie Sato; Yuichi Kobayashi

• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 256 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)80091-x

✦ Synopsis

Palladium-catalyzed reaction of u-substituted Y-trimethylsilylated allylic carbonates with carbonucleophiles took place regioselectively at the a-carbon. Reaction of formic acid took place at Y-carbon to afford allylic