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Preparation of a Functionalized Tetracyclic Intermediate for the Synthesis of Rhodexin A

โœ Scribed by Jung, Michael E.; Chu, Hiufung V.


Book ID
118124942
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
116 KB
Volume
10
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES


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In our previous studies on gibberellin synthesis we have described a general approach to the construction of the ring A lactone system as present in gibberellins such as Gibberellic acid and Gibberellin A4 (l), based on the reductive alkylation of a P-methoxybenzoic acid 192 . We have also described

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In the course of the cited synthesis of (\*)-la, compound 3a was in fact obtained as a major epimer, along with 3b. The synthesis of (&)-la was then carried on with the minor epimer 3b [4].