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Preparation of 4,6-dehydro-2-adamantanone and 2,4,6,9-bis-dehydroadamantane by pyrolysis of adamantanespirodiazirines

✍ Scribed by S. D. Isaev; G. G. Kolyada; S. S. Novikov; A. G. Yurchenko


Book ID
112438443
Publisher
Springer
Year
1974
Tongue
English
Weight
74 KB
Volume
23
Category
Article
ISSN
1573-9171

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Preparation and structure elucidation of
✍ Bruce Gaede; Rodger Henry; Steven A. Chamberlin πŸ“‚ Article πŸ“… 2000 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 179 KB

## Abstract The tricyclic title compound, a symmetrical dispiro oxygen heterocycle, was isolated as a byproduct in the hydrogenation of furfuryl alcohol in the presence of hydrochloric acid. NMR studies and single crystal X‐ray analysis have established the relative stereochemistry of the two ketal