## Abstract The four deuteriated 4‐phenylbutyric [2,3‐^2^H~2~]‐, [4,4‐^2^H~2~]‐, [2,3,4,4‐^2^H~4~]‐, and [2,2,3,3,4,4‐^2^H~6~]‐acids have been synthesized in high isotopic purity by utilizing crossed Kolbe electrolysis of methyl hydrogen [^2^H~0~]‐, [2,3‐^2^H~2~], and [2,3,3,3‐^2^H~4~]‐succinates a
Preparation of 4,4′-diaminodiphenylmethane-(2H4) for use as internal standard in the quantification of 4,4′-diaminodiphenylmethane
✍ Scribed by Marco Natangelo; Renzo Bagnati; Roberto Fanelli; Marco Gavinelli; Claudia Ulbricht; Emilio Benfenati
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- French
- Weight
- 170 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-2135
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✦ Synopsis
A simple method has been developed for the synthesis of 4,4'-diarninodiphenylmethane-(2Hq) for analytical purposes in gas chromatography-negative ion chemical ionization mass s ectrometry usin deutero-h drochloric acid in deuterated metkanol. The reaction was aromatic rings was observed after eight days in these conditions, using mass spectrometry (MS) and nuclear magnetic resonance (NMR) spectroscopy.
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