𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Preparation of (2E,4E,6S,7S,10E,12E,14S,15S,1′S)-7,15-Bis(1′-hydroxymethylethyl)-6,14-dimethyl-8,16-dioxa-2,4,10,12-cyclohexadecatetraene-1,9-dione. – A Building Block for the Synthesis of Elaiophylin

✍ Scribed by Jackson, Richard F. W. ;Sutter, Marius A. ;Seebach, Dieter

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
908 KB
Volume
1985
Category
Article
ISSN
0947-3440

No coin nor oath required. For personal study only.

✦ Synopsis

Bis( 1'-h ydrox y met h y le t hyl)-6,14-dimet hy1-8,16-dioxa-2,4,10,12-cyclohexadecatetraene-1,9-dione. -A Building Block for the Synthesis of Elaiophylin

📜 SIMILAR VOLUMES

Synthese von (2E,4E,6S,7R,10E,12E,14S,15
Synthese von (2E,4E,6S,7R,10E,12E,14S,15R)-6,7,14,15-Tetramethyl-8,16-dioxa-2,4,10,12-cyclohexadecatetraen-1,9-dion. Ein Modellsystem für Elaiophylin
✍ Sutter, Marius A. ;Seebach, Dieter 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 610 KB

## Abstract Ausgehend von (R)‐(−)‐3‐Hydorxybuttersäure‐ethylester (**6**) wurde die Titelverbindung **5** über 11 Stufen in einer Gesamtausbeute von 9.5% synthetisiert. Die Kettenverlängerung um vier C‐Atome wird dabei durch Wittig‐Reaktionen (**10** → **11**, __13__ → __14__), die Methylverzweigun

Synthesis and [4+2] Cycloaddition of (2R
Synthesis and [4+2] Cycloaddition of (2R,2′R)-N,N′-Fumaroylbis[fenchane-8,2-sultam] (=(2E)-1,4-Bis[(3aS,6S,7aR)-1,4,5,6,7,7a-hexahydro-7,7-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzothiazol-1-yl]but-2-ene-1,4-dione) to Cyclopentadiene
✍ Anna M. Piątek; Agnieszka Chojnacka; Christian Chapuis; Janusz Jurczak 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 167 KB

## Abstract The now corrected X‐ray structure of (2__R__)‐bornane‐10,2‐sultam ((−)‐**1a**), as well as that of its already published __N__‐crotonoyl derivative (−)‐**1d**, were compared with those of the newly synthesized (2__R__)‐fenchane‐8,2‐sultam ((+)‐**5a**), as well as its __N__‐crotonoyl der

Preparation via Diastereoselective Hydro
Preparation via Diastereoselective Hydrogenation, Absolute Conformation and Configuration of Exogeneous Anabolic Zeranol ((3S, 7R)-3,4,5,6,7,8,9,10,11,12-Decahydro-7,14,16-trihydroxy-3-methy-1H-2-benzoxacyclotetradecin-1-one)
✍ Günther Snatzke; Cristina Angeli; Enio Decorte; Flavio Moimas; Biserka Kojié-Pro 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 German ⚖ 834 KB

Hydrogenation of the ketone group in di-0-benzylderivative (8) of the known macrocyclic lactone zeralenone (7) using a novel chiral borane complex 3.BH3, prepared in situ, proceeded at lower temperatures with moderate diastereoselectivity ( -40%, d.e. at -60"). Unsaturated diastereomers 9 and 10 wer

Crystal Structures of 3.0.CO;2-Z/asset/e
Crystal Structures of 3.0.CO;2-Z/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l6migq&s=c6023d23614cc5febe987fafc1b321310df66e88" class="inlineGraphic">{[Cd(phen)](C6H8O4)3/3} and 3.0.CO;2-Z/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l6migr&s=ca7048152611c2fb5494587a82e9d48966405110" class="inlineGraphic">{[Cd(phen)](C7H10O4)3/3} · 2H2O with C6H10O4 = Adipic Acid and C7H12O4 = Pimelic Acid
✍ Yue-Qing Zheng; Wen-Han Liu; Jian-Li Lin 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 123 KB 👁 2 views

Two coordination polymers 1 ϱ {[Cd(phen)](C 6 H 8 O 4 ) 3/3 } (1) and 1 ϱ {[Cd(phen)](C 7 H 10 O 4 ) 3/3 } • 2H 2 O (2) were structurally characterized by single crystal X-ray diffraction methods. In 1 (C2/ c (no. 15), a ϭ 16.169(2) A ˚, b ϭ 15.485(2) A ˚, c ϭ 14.044(2) A ˚, β ϭ 112.701(8)°, U ϭ 324

Rapid and Simple Isolation of the Crysta
Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na15[Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l566t6&s=c0a09f77518ccacb50e822358608409f8e1c0a41" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l566t6&s=3b4dd445e7e4356504ec58daf107b378c9736f7b" class="inlineGraphic">O462H14(H2O)70]0.5 [Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-3.gif?v=1&t=h5l566t6&s=32c4cd6315aa03537e50d3683e9830279c928f78" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-4.gif?v=1&t=h5l566t7&s=3a1388422ef00ab21b32f2e8ba73a564490bf0c1" class="inlineGraphic">O457H14(H2O)68]0.5 · ca. 400 H2O and Na22[Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-5.gif?v=1&t=h5l566t7&s=2f041805f3359c66af741d31ef3916871c113c35" class="inlineGraphic">Mo3.0.CO;2-%23/asset/equation/tex2gif-stack-6.gif?v=1&t=h5l566t7&s=e3f6eced1d8e1eea086310b68afe457fcdf2951e" class="inlineGraphic">O442H14(H2O)58] · ca. 250 H2O
✍ Achim Müller; Samar K. Das; Vladimir P. Fedin; Erich Krickemeyer; Christian Beug 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 167 KB 👁 3 views

The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê