𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Preparation of 2-deoxy-β-d-lyxo-hexosides (2-deoxy-β-d-galactosides)

✍ Scribed by David Crich; Timothy J. Ritchie

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
211 KB
Volume
190
Category
Article
ISSN
0008-6215

No coin nor oath required. For personal study only.

✦ Synopsis

With a view to the eventual synthesis of the trisaccharide chain of the antitumor antibiotic olivomycin A1 (1)) we have studied the preparation2 of heptulosonic acid 0-glycosides and their stereoselective radical decarboxylation3 to 2-deoxy-EDarubino-hexosides (2deoxy-/3-D-glucosides). We now report the preparation of 2deoxy-/3-D-lyxo-hexosides (2-deoxy+?-D-galactosides), relevant to the disaccharide chain of olivomycin A, and improvements in the synthesis of heptulosonic acids.

📜 SIMILAR VOLUMES

Crystal structure of 2-deoxy-β-d-lyxo-he
Crystal structure of 2-deoxy-β-d-lyxo-hexose (2-deoxy-β-d-galactose)
✍ Raffaella Puliti; Carlo A. Mattia; Guido Barone 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 344 KB

2-Deoxy-P-D-lyxo-hexose (2-deoxy+-D-galactose, C,H,,O,), M, = 164.16, is monoclinic, P2, with a = 9.811(l), b = 6.953(l), c = 5.315(l) A, p = 91.58(2)", V = 362.5(l) A3, Z = 2, and D, = 1.504 g.cme3. The structure was solved by direct methods (MULTAN 79) and refined to R = 0.032 for 800 observed ref

1H NMR Study of 2-Deoxy-D-Arabino-Hexopy
1H NMR Study of 2-Deoxy-D-Arabino-Hexopyranose (2-Deoxy Glucopyranose), 2-Deoxy-D-Lyxo-Hexopyranose (2-Deoxy Galactopyranose) and 2′-Deoxy Lactose. Shift Increment Studies in 2-Deoxy Carbohydrates
✍ A. De Bruyn; M. Anteunis 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 287 KB 👁 1 views

## Abstract Complete analyses of the ^1^H n.m.r. spectra at 300 MHz of D~2~0 solutions of 2‐deoxy‐D‐arabino‐hexopyranose, 2‐deoxy‐D‐lyxo‐hexopyranose and 2′‐deoxy lactose. Chemical shifts in the deoxy monosaccharides and in 2′‐deoxy lactose are compared with those previously obtained in the parent