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1H NMR Study of 2-Deoxy-D-Arabino-Hexopyranose (2-Deoxy Glucopyranose), 2-Deoxy-D-Lyxo-Hexopyranose (2-Deoxy Galactopyranose) and 2′-Deoxy Lactose. Shift Increment Studies in 2-Deoxy Carbohydrates

✍ Scribed by A. De Bruyn; M. Anteunis

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
287 KB
Volume
84
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

Complete analyses of the ^1^H n.m.r. spectra at 300 MHz of D~2~0 solutions of 2‐deoxy‐D‐arabino‐hexopyranose, 2‐deoxy‐D‐lyxo‐hexopyranose and 2′‐deoxy lactose. Chemical shifts in the deoxy monosaccharides and in 2′‐deoxy lactose are compared with those previously obtained in the parent aldohexopyranoses, glucobioses and D‐galactopyranosyl‐D‐glucoses. Increment values are suggested in order to predict chemical shifts in 2‐deoxy derivatives from the well known rules for aldohexopyranoses.

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