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Preparation of 1-bromoadamantane and adamantane-1-carboxylic acid from 1-adamantyl nitrate

✍ Scribed by N. V. Stulin; A. V. Yudashkin; A. K. Shiryaev; I. K. Moiseev; A. S. Petrov


Book ID
112401630
Publisher
Springer
Year
1984
Tongue
English
Weight
237 KB
Volume
18
Category
Article
ISSN
0091-150X

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A new, convenient on-column method using kieselguhr (Extrelut ~, Merck) has been developed for the synthesis of l-aminocyclopentane-1-[ ~ tC]carboxylic acid ([t ~C]ACPC) from [J ~C]HCN. The whole synthetic procedure, including the trapping and reaction of [~ ~C]HCN as well as the following extractio