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Preparation, crystal structures and electrical conducting properties of new charge-transfer salts: (ET)2·SO3CF3 and (ET)·ClO4

✍ Scribed by Chuyang Jia; Deqing Zhang; Wei Xu; Daoben Zhu


Book ID
117539941
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
269 KB
Volume
140
Category
Article
ISSN
0379-6779

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Three new charge transfer salts of tetrathiafulvalene (TTF)based donors with selenocyanate-metal complex anions have been synthesized. The salts have been characterized as BEDT-TTF 4 [Cr(NCSe) 6 ] . CH 2 Cl 2 , II, TTF 3 [Cr(NCSe) 4 phen] 2 , III and BEDT-TTF 2 [Cr(NCSe) 4 phen] Á CH 2 Cl 2 , IV, wh