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Preparation, characterization, and solution behavior of tri-tert-butylphosphine complexes of copper(I) halides and crystal structure of bromo(tri-tert-butylphosphine)copper(I) tetramer

✍ Scribed by Goel, Ram G.; Beauchamp, Andre L.


Book ID
120690711
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
805 KB
Volume
22
Category
Article
ISSN
0020-1669

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The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati