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Preparation, Characterization, and Crystal Structures of the SO3NHF− and SO3NF2− Ions

✍ Scribed by Ralf Haiges; Ross Wagner; Jerry A. Boatz; Muhammed Yousufuddin; Markus Etzkorn; G. K. Surya Prakash; Karl O. Christe; Robert D. Chapman; Mark F. Welker; Charles B. Kreutzberger

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
141 KB
Volume
118
Category
Article
ISSN
0044-8249

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✦ Synopsis

on the occasion of his 70th birthday

Recently, a new class of materials having high-energy, gembis(difluoroamino)-substituted heterocyclic nitroamines, has gained attention for use as high-energy oxidizers: HNFX [1, 2] and TNFX [3] have been synthesized under strongly acidic conditions from their corresponding ketone derivatives by using an excess of difluoroamine. [4] HNF 2 is a shock-sensitive and thermally unstable gaseous compound, [5,6] which can be generated from different precursors, for example, tetrafluorohydrazine, [7] N,N-difluorourea, [8] N,N-difluorocarbamates, [9] or trityldifluoroamine. [10] Of these precursors, only trityldifluoroamine is a stable,

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