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Preparation and Structure of β-Peptides Consisting of Geminally Disubstituted β2,2- and β3,3-Amino Acids: A Turn Motif for β-Peptides

✍ Scribed by Dieter Seebach; Stefan Abele; Thierry Sifferlen; Martin Hänggi; Sibylle Gruner; Paul Seiler


Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
382 KB
Volume
81
Category
Article
ISSN
0018-019X

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α,β-Dehydro-amino acid residues in the d
✍ Pushkar Sharma; Punit Narula; Tej P. Singh 📂 Article 📅 1994 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 470 KB

The dehydro-residue containing peptides N-Ac-dehydro-Phe-L-Leu-OCH3 ( I ) and N-Acdehydro-Phe-NorVal-OCH, (11) were synthesized by the usual workup procedures. The peptides crystallize from their solutions in methanol in space group P6,: ( I ) a = b = 12.528(2) A, c = 21.653(5) A; (11) a = b = 12.53