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Preparation and structure of the compounds SrVO3 and Sr2VO4

โœ Scribed by M.J. Rey; Ph. Dehaudt; J.C. Joubert; B. Lambert-Andron; M. Cyrot; F. Cyrot-Lackmann

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
382 KB
Volume
86
Category
Article
ISSN
0022-4596

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Phase-pure \(\mathrm{Ba}_{2} \mathrm{VO}_{4}\) has been synthesized by hydrogen reduction of a mixture of \(\mathrm{Ba}_{3} \mathrm{~V}_{2} \mathrm{O}_{8}\) and \(20 \%\) excess \(\mathrm{BaCO}_{3}\) at \(12000-1250^{\circ} \mathrm{C}\), and its crystal structure, designited as \(\beta-\mathrm{Ba}_{