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Preparation and reactivity of some functionalized halomethylzinc carbenoids

✍ Scribed by AndréB. Charette; André Beauchemin; Jean-François Marcoux

Book ID
104260657
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
212 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Various mixed diorganozinc reagents were prepared by the irradiation of diethylzinc and functionalized alkyl iodides. These species were shown to react with dihalomethane to form zinc carbenoids in a highly regioselective manner. In some cases, the latter reagents proved to be effective cyclopropanating reagents.

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