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Naphthalene-catalysed lithiation of functionalized chloroarenes: regioselective preparation and reactivity of functionalized lithioarenes

✍ Scribed by Albert Guijarro; Diego J Ramón; Miguel Yus

Book ID
108371563
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
982 KB
Volume
49
Category
Article
ISSN
0040-4020

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Various mixed diorganozinc reagents were prepared by the irradiation of diethylzinc and functionalized alkyl iodides. These species were shown to react with dihalomethane to form zinc carbenoids in a highly regioselective manner. In some cases, the latter reagents proved to be effective cyclopropana